Ⅱ. Sodium hydroxide solution can react with magnesium chloride to generate white magnesium hydroxide precipitate; Therefore, sodium hydroxide solution was added to the supernatant after the experiment in step 1 to produce white precipitate, which indicated that the crude salt contained magnesium chloride.
Conclusion and Reflection (1) Magnesium carbonate is slightly soluble in water, and white precipitation also occurs; Therefore, the experiment in the first step 1 can't conclude that the conjecture ① holds;
(2) Barium carbonate precipitate can react with hydrochloric acid to generate barium chloride, water and carbon dioxide;
Answer: Ⅰ. Evaporation;
Ⅱ. Sodium hydroxide solution
Conclusion and Reflection (1) Magnesium carbonate is slightly soluble in water;
(2)BaCO3+2HCl=BaCl2+H2O+CO2↑