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The reason why maltitol has higher calories than ordinary sugars

Both are high in fat and starch.

Maltitol, like sugar, is a carbohydrate containing calories. It also contains a certain amount of caloric energy. It has high fat and starch content. Large amounts of maltitol can also indirectly cause blood sugar to rise. Generally, The fat and starch content in sugars are very high and contain a large amount of caloric energy, so maltitol has fewer calories than ordinary sugars.

Maltitol is used as a sweetener for high-fat foods such as ice cream, cream pastries, toffee, etc., and can have a sweetening effect.