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What is the basic unit of starch? Is the basic unit of polysaccharide glucose?
Starch consists of α- 1 4-linked glucose. It can be said that the monomer of starch is glucose.

There are many kinds of polysaccharides, a large part of which are only composed of glucose (cellulose, glycogen); Some of them also contain other groups, such as xylan (linked only by xylose), chitosan (deacetylated from chitin and containing amino groups), heparin and so on.