B. According to the data, substances containing trivalent arsenic are toxic, and arsenic is an oxide of arsenic, which is toxic, so arsenic contained in arsenic may be trivalent arsenic, so b is correct;
C, shrimp contains pentavalent arsenic, non-toxic, edible, so C is wrong;
D, in the reaction, the valence of arsenic decreases, and the valence of an element in vitamin C increases. In the reaction, vitamin C is used as a reducing agent, so D is wrong;
So choose B.